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71.
介绍和评述了诊断含能材料热分解和推进剂燃烧波结构的方法、仪器和研究进展,以及含能材料和推进剂热分解和燃烧波结构的研究结果,探讨了燃烧机理研究方法的发展方向。提出需要不断完善和更新推进剂燃烧的诊断方法,以获得更为全面的接近真实条件下推进剂燃烧的有效信息。附参考文献14篇。 相似文献
72.
T.V. Choudhary A.K. Santra C. Sivadinarayana B.K. Min C.-W. Yi K. Davis D.W. Goodman 《Catalysis Letters》2001,77(1-3):1-5
Ammonia decomposition on Ir(100) has been studied over the pressure range from ultrahigh vacuum to 1.5 Torr and at temperatures ranging from 200 to 800 K. The kinetics of the ammonia decomposition reaction was monitored by total pressure change. The apparent activation energy obtained in this study (84 kJ/mol) is in excellent agreement with our previous studies using supported Ir catalysts (Ir/Al2O3 82 kJ/mol). Partial pressure dependence studies of the reaction rate yielded a positive order (0.9±0.1) with respect to ammonia and negative order (–0.7 ±0.1) with respect to hydrogen. Temperature-programmed desorption data from clean and hydrogen co-adsorbed Ir(100) surfaces indicate that ammonia undergoes facile decomposition on both these surfaces. Recombinative desorption of N2 is the rate-determining step with a desorption activation energy of 63 kJ/mol. Co-adsorption data also indicate that the observed negative order with respect to hydrogen pressure is due to enhancement of the reverse reaction (NH
x
+ H NH
x+1, x=0–2) in the presence of excess H atoms on the surface. 相似文献
73.
针对离散Hopfield 神经网络(DHNN) 的权值设计问题, 提出一种改进型学习算法, 并在DHNN动力学分析的基础上设计该学习算法. 利用矩阵分解的方法(MD) 得到正交矩阵, 并采用得到的正交矩阵直接计算DHNN的权值矩阵. 通过该学习算法得到的权值矩阵, 可以很好地存储训练样本的信息, 使测试样本收敛到稳定点. 该学习算法不需要进行分块计算, 减少了计算步骤和计算量, 降低了网络的迭代次数, 从而提高了网络运行速度. 最后, 将该学习算法应用于水质评价, 验证了其有效性和可行性. 相似文献
74.
Coordination between strategic forest management and tactical logistic and production planning in the forestry supply chain 总被引:1,自引:0,他引:1
Jiehong Kong Mikael Rönnqvist 《International Transactions in Operational Research》2014,21(5):703-735
In this paper, we study the coordination mechanism in the forestry supply chain between strategic forest management and tactical production planning. We first formulate an integrated model to establish a theoretical benchmark for performance of the entire supply chain. It is a mixed integer programming model that involves harvesting, bucking, transportation, production, and sales decisions for both tactical and strategic planning levels. We then present two sequential approaches S‐A and S‐B where the coordination is done through internal pricing. S‐A is the approach currently used in practice where harvesting in the forest is the main driver of the supply chain activities and internal pricing is introduced to control bucking decision in a separate stage. In contrast, S‐B takes downstream demand information into consideration and internal pricing directly influences harvesting decision in the first stage. In order to find the appropriate setting of internal pricing that leads to the system optimum, we suggest two heuristics H‐I and H‐II. The internal pricing in H‐I is based on dual values and in H‐II, it is derived from a Lagrangian decomposition. A real‐life case study in the Chilean forestry industry is used to compare the results of different approaches. It is shown that the new sequential approach S‐B generates as good feasible solution as that obtained from the integrated approach but in much less time. Both heuristics H‐I and H‐II bring about near‐optimal feasible solutions. H‐II also provides optimistic bound of the optimal objective function value, which can be used as a measure of the solution quality. 相似文献
75.
为了准确地提取出故障特征,把局域均值分解算法应用于机械故障振动信号的特征提取中.然而在对信号进行局域均值分解时,由于端点的趋势无法预知,在分解时会污染到整个信号序列,而且滑动平均造成了信号的过平滑处理,导致故障特征不能准确地提取.采用波形匹配解决端点处信号的走势,之后再利用线性插值求得信号的局域均值函数与包络函数,通过在Matlab环境下仿真调幅信号验证了该算法在端点处能很好的保持原有信号的特征;并采用实际的机械振动信号进行实验验证,引入端点效应评价指标,根据分解后的生产函数与原信号的相关系数验证了改进的局域均值分解更能准确地提取故障特征. 相似文献
76.
Ti-oxides incorporated within the framework of microporous zeolites and mesoporous molecular sieves were found to exhibit
high and unique photocatalytic activity for the decomposition of NO into N2 and O2 as well as the reduction of CO2 with H2O to produce CH4 and CH3OH. Spectroscopic investigations of these catalytic systems using photoluminescence, UV-vis, XAFS (XANES and FT-EXAFS) and
IR analyses revealed that the charge transfer excited state of the isolated tetra-coordinated Ti-oxides plays a vital role
in these photocatalytic reactions. The reactivity of such Ti-oxides was found to depend strongly on their local structures
which were controlled by the unique framework structures of the micro- and mesoporous material supports. 相似文献
77.
In this study the methyl tert-butyl ether (MTBE) decomposition over H3PW12O40 was carried out in a cellulose acetate membrane reactor. The permeability of methanol through the cellulose acetate membrane was about 30 and 300 times higher than that of either isobutene or MTBE, respectively. The isobutene selectivity in the fixed bed reactor was only slightly higher than the methanol selectivity due to the side reaction. In the cellulose acetate membrane reactor, however, the isobutene selectivity in the rejected stream was 68% and the methanol selectivity in the permeated stream was up to 97%. The MTBE conversion in the membrane reactor was about 7% higher than that in the membrane-free fixed bed reactor under the same reaction conditions. The enhanced performance of the membrane reactor in this reversible reaction was mainly due to the selective permeation of methanol which resulted in a methanol-deficient condition suppressing MTBE synthesis reaction. 相似文献
78.
The phase-separation behavior of poly(methyl methacrylate)/poly(α-methyl styrene-co-acrylonitrile) (PMMA/α-MSAN) blends with two different compositions was studied by time-resolved small angle light scattering (SALS) in the spinodal decomposition (SD) regime from 160 to 210 °C. The rheological function (WLF-like equation) was introduced into the processing of light scattering data. It was found that the WLF-like equation was applicable to describe the temperature dependence of apparent diffusion coefficient Dapp and the relaxation time τ of normalized scattering intensity (I(t)−I(0))/(Im−I(0)) at the early stage of SD, as well as the relaxation time τ of maximum scattering intensity Im and characteristic scattering vector qm with Im at the late stage of SD for PMMA/α-MSAN blends with two different compositions. This is in consistence with the phase-separation behavior of PMMA/SAN reported in our previous paper. 相似文献
79.
Manganese ferrite nanoparticles synthesized through a nanocasting route as a highly active Fenton catalyst 总被引:2,自引:0,他引:2
Teresa Valds-Solís Patricia Valle-Vign Sonia lvarez Gregorio Marbn Antonio B. Fuertes 《Catalysis communications》2007,8(12):2037-2042
Spinel ferrite MnFe2O4 nanoparticles were synthesized by means of a nanocasting technique using a low-cost mesoporous silica gel as a hard template. The magnetic nanoparticles, of <10 nm diameter and with a surface area of around 100 m2/g, were tested as a heterogeneous Fenton catalyst for the decomposition of hydrogen peroxide under neutral and basic conditions. This catalyst shows a much higher activity than previous heterogeneous catalysts reported in the literature, which is mainly ascribed to its small particle size. Furthermore, the magnetic catalyst can be easily separated from the reaction medium by means of an external magnetic field. The effects of residual silica and the purity of the catalyst (hematite formation) on catalytic activity have been studied and correlated. The results obtained show this catalyst to be a suitable candidate for the removal of pollutants in wastewaters by means of the Fenton heterogeneous reaction. 相似文献
80.
研究了基于最大互信息图像配准的理论和实现算法,提出了将小波分解与之相结合的算法,证明了该算法优于基于最大互信息的图像配准。通过实验数据比较可以得出,提出的基于小波分解和最大互信息的图像配准的算法可以有效地提高配准的速度和具有较好的配准效果。 相似文献